Blocking neutralizes background variables that can not be eliminated by randomizing. It does so by spreading them across the experiment.
You can think of a block as an kind of uncontrolable factor that is added to the experiment. A block is ususally used when this uncontrolable factor cannot be avoided during the experiment, so it is incorporated into the experiment in a controlled way. The idea is to pull the variation due to the blocks out of the expermental error in order to reduce the experimental error and give the test more power.
Common examples of when blocking factors are used:
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