I don’t know of an official educational requirement for Six Sigma training. I wouldn’t put any educational requirements on candidates for Six Sigma green belt training. For black belt training (and beyond), I expect pretty much any 4-year degree would be sufficient to “qualify”.
When choosing candidates for any level of Six Sigma training, I’d look for these:
Need to have some mathematical aptitude.
Should be computer literate.
Exhibit leadership potential.
Demonstrate willingness to work in a team environment.
Open to change.
Good communication skills (verbal and written).
Hope this helps.
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